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    董金梅, 罗丹, 徐洪钟, 刘贵起. 碱激发胶凝材料固化铜污染土试验研究[J]. 应用基础与工程科学学报, 2023, 31(2): 498-508. DOI: 10.16058/j.issn.1005-0930.2023.02.020
    引用本文: 董金梅, 罗丹, 徐洪钟, 刘贵起. 碱激发胶凝材料固化铜污染土试验研究[J]. 应用基础与工程科学学报, 2023, 31(2): 498-508. DOI: 10.16058/j.issn.1005-0930.2023.02.020
    DONG Jin-mei, LUO Dan, XU Hong-zhong, LIU Gui-qi. Test Study on Solidification of Copper Contaminated Soil by Alkali Activated Cementitious Materials[J]. Journal of Basic Science and Engineering, 2023, 31(2): 498-508. DOI: 10.16058/j.issn.1005-0930.2023.02.020
    Citation: DONG Jin-mei, LUO Dan, XU Hong-zhong, LIU Gui-qi. Test Study on Solidification of Copper Contaminated Soil by Alkali Activated Cementitious Materials[J]. Journal of Basic Science and Engineering, 2023, 31(2): 498-508. DOI: 10.16058/j.issn.1005-0930.2023.02.020

    碱激发胶凝材料固化铜污染土试验研究

    Test Study on Solidification of Copper Contaminated Soil by Alkali Activated Cementitious Materials

    • 摘要: 利用经济环保的工业副产品粉煤灰(FA)、矿渣微粉(GGBS)修复Cu污染场地,减少Cu污染对周围环境的影响,通过开展Ca(OH)2、NaOH分别激发FA、GGBS、FA-GGBS固化铜(Cu)污染土的无侧限抗压强度试验,Cu2+浸出试验和固化土微观结构试验,研究碱激发胶凝材料固化Cu污染土的固化效果.结果表明:FA、GGBS、FA-GGBS都能较好提高Cu污染土的抗压强度,FA-GGBS复合固化比FA、GGBS单独固化Cu污染土抗压强度高,可提高约30%;采用NaOH比采用Ca(OH)2激发FA-GGBS水反应慢,因此工期短采用Ca(OH)2激发效果好,工期较长采用NaOH激发FA-GGBS固化Cu污染土效果好;酸溶液淋溶作用下固化土中Cu2+的释放行为与FA-GGBS固化剂掺量和固化污染土养护龄期相关,掺量增加和龄期增长,Cu2+浸出浓度显著降低,碱激发胶凝材料对Cu2+有良好的稳定作用;扫描电镜试验结果表明,随着Cu2+含量的增加,碱激发胶凝材料固化Cu污染土中孔隙逐渐增多,导致强度和稳定效果降低.碱激发胶凝材料固化Cu污染土的试验研究,对Cu污染场地的治理和修复具有重要的意义.

       

      Abstract: The potential use of two industrial waste by-products, namely, fly ash(FA) and ground granulated blast furnace slag(GGBS),as alternative green binders in solidification of copper contaminated soil is presented.To investigate the effectiveness of the solidification of copper contaminated soil amended by FA,GGBS and FA-GGBS activated with Ca(OH)2,NaOH,The unconfined compressive strength test, copper leaching and scanning electron microscopy(SEM) imaging tests are conducted.The results show that FA,GGBS and FA-GGBS can improve the compressive strength of copper contaminated soil.The compressive strength of copper contaminated soil amended by FA-GGBS is higher than that of FA and GGBS alone, which can be increased by about 30%.The hydration reaction of FA-GGBS activated with NaOH is slower than that activated with Ca(OH)2.When the curing time is 28 days, NaOH can be used to activate FA-GGBS to solidify copper contaminated soil, When the curing time is 7 days, Ca(OH)2 can be used.The leaching performance of Cu2+ in soil under acid solution leaching is related to the dosage of FA-GGBS and the curing time of contaminated soil.with the increase of dosage and curing time, the leached Cu2+ concentration decreases significantly.Aalkali-activated cementitious material has a good stabilization effect on copper contaminated soil.SEM test results show that with the increase of Cu2+ concentration, the porosity of copper contaminated soil increase gradually, resulting in the decrease of strength and stabilization effect.The study provides a feasible method for the solidification and restoration of copper contaminated soil.

       

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