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    黏土表层无扰动斥水改性及其水力特性

    Water Repellent Modification of Clay Surface Without Disturbance and Its Hydraulic Properties

    • 摘要: 斥水性土壤因其防水、抗渗和抑制蒸发等特性而备受关注.然而,传统制备方法通常需对土体进行干燥处理并与斥水剂混合搅拌,这一过程易导致黏土结构破坏并限制其应用范围.把十八胺粉末覆盖于土体表层,当表层温度达到十八胺熔点以上时,十八胺熔化并入渗至表层土体,形成无扰动斥水改性黏土.对改性土水力性质的研究表明:试样初始含水率越高,斥水改性所需的时间越长,但含水率并不影响最终的改性效果.黏土表层斥水改性能有效抑制土壤崩解,但受内部封闭气体影响,土壤崩解率可能出现负值.此外,该无扰动改性黏土兼具熔融十八胺表面覆膜和晶体孔隙堵塞双重阻水机制.研究结果可为原状土及易风化岩石斥水改性提供参考.

       

      Abstract: Hydrophobic soils have drawn extensive attention due to their properties of waterproofing,seepage resistance,and evaporation inhibition.However,conventional methods for preparing hydrophobic soil require drying and mixing with water-repellent agents,which can damage the clay structure and limit its application.This study employed a technique where octadecylamine (ODA) powder was applied to the soil surface.When the surface temperature reached the melting point of ODA,the powder melted and infiltrated the surface soil to form undisturbed hydrophobic modified clay.Investigations into the hydraulic properties of the modified soil demonstrated that a higher initial moisture content prolonged the time required for hydrophobization but did not affect the final modification effect.The surface hydrophobic modification effectively prevented soil disintegration,although the measured soil disintegration rate could exhibit negative values due to the influence of internal trapped air.Beyond the water-repellent nature,the undisturbed modified clay exhibited a dual water-blocking mechanism comprising a surface coating by molten ODA and pore clogging by crystals.The findings provide a valuable reference for the hydrophobic modification of intact soils and easily weathered rocks.

       

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