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    阴燃处置含油污泥的自维持特性及影响因素

    Study on Self-Sustaining Characteristics and Influencing Factors of Oily Sludge Disposal by Smoldering

    • 摘要: 目前,含油污泥产量大且环境危害高,亟需高效、低能耗的处置技术.以含水率为16.5%的含油污泥为研究对象,在阴燃小试装置上开展实验,考察不同物料热值及达西空气流速对阴燃自维持特性的影响,并分析阴燃产物及处置效果;在100kg阴燃装置上开展中试实验,并评估其经济性.结果表明,当热值为2 794~5 589kJ/kg和达西空气流速为1.87~2.49cm/s时,系统可实现稳定阴燃,石油烃去除率达98%以上.尾气中的不凝性气体以甲烷、正己烷等正构烷烃为主,冷凝液中C11~C20占比为46.38%.中试实验验证了小试结果的稳定性,阴燃过程稳定,石油烃去除率为99.54%.中试综合处置成本约为288元/m3,相比氧化、焚烧及超临界萃取等方法更具经济优势.该研究为阴燃技术在含油污泥处置中的实际应用提供理论参考.

       

      Abstract: At present,oily sludge has large output and high environmental harm,and it is in urgent need of high efficiency and low energy consumption disposal technology.Taking oily sludge as the object,this study conducted experiments on a smouldering small test unit to explore the effects of different calorific value of materials and Darcy air flow rate on smouldering self-maintenance,and analyzed smouldering products and disposal effects.Pilot tests were carried out on a 100kg smouldering unit,and economic analysis was conducted.The results show that when the calorific value is 2 794~5 589kJ/kg and the Darcy air flow rate is 2.11cm/s,and the calorific value is 5 589kJ/kg and the Darcy air flow rate is 1.87~2.49cm/s,the smolder can be stable,and the removal rate of petroleum hydrocarbons can reach more than 98%.The non-condensing gas in the tail gas is mainly methane,n-hexane and other normal alkane,and the carbon number of the condensate is C11~C20,which accounts for 46.38%.When the calorific value of oily sludge is 3 912kJ/kg and the Darcy air flow rate is 2.11cm/s,it can stably smold,the removal rate of petroleum hydrocarbon is 99.54%,and the comprehensive disposal cost of pilot test is about 414yuan/m3,which is more economical than oxidation,incineration,supercritical extraction and other methods.The research results can provide theoretical reference for the practical application of smoldering technology in oily sludge disposal.

       

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