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    原位热脱附修复过程蒸汽迁移特征的模型试验研究

    Model Test of Steam Migration during In-situ Thermal Desorption Remediation

    • 摘要: 蒸汽在土体中的热湿迁移特征是影响有机污染场地蒸汽注入修复效果的关键因子.采用玻璃珠模拟多孔介质土体开展系列模型试验,研究了饱和蒸汽、过热蒸汽和混合蒸汽3种不同类型蒸汽注入时温度场演变过程.试验结果表明:基于温度场分布特征,多孔介质可划分为蒸汽高温区、温度过渡区和环境温度区,过热蒸汽注入时蒸汽高温区内会出现温度高于373K的过热蒸汽区;蒸汽注入流量主要影响蒸汽高温区和温度过渡区面积;过热蒸汽中添加增溶剂丙二醇能够显著增大过热蒸汽区面积和最高温度,但多孔介质升温速率变慢.对比分析蒸汽性质对多孔介质中蒸汽迁移过程的影响程度,结果表明:蒸汽注入温度和注入流量对多孔介质最高温度、蒸汽高温区面积的影响程度显著;添加丙二醇具有双重效应,一方面会显著提高多孔介质的最高温度,提高过热蒸汽区的热脱附修复效率;另一方面会抑制蒸汽高温区的发展.研究成果以期有助于为优化蒸汽注入土壤修复工程设计提供理论依据.

       

      Abstract: The heat and moisture transport characteristics of steam in soil is a key factor affecting the remediation efficiency of organic contaminated sites using steam injection technology.This study carried out a series of model experiments using glass beads to simulate porous media,to investigate the tempo-spatial distribution of temperature during the injection of three types of steam:saturated steam,superheated steam and mixed steam.The experimental results reveal that the porous media can be divided into three zones according to the characteristics of temperature distribution:a high temperature zone,a temperature transition zone,and an ambient temperature zone.During superheated steam injection,a superheated steam zone emerges within the high temperature zone,where temperature exceeds 373K.The steam injection rate primarily affects the area of the high temperature and temperature transition zones.The addition of propylene glycol as a solubilizer to superheated steam significantly increases the area of the superheated steam zone and the maximum temperature within the porous media,although it results in a slower heating rate.Comparative analysis of steam properties impact on the steam migration process indicates that both the steam injection temperature and injection rate significantly influence the maximum temperature and the area of the high temperature zone.The inclusion of propylene glycol demonstrates dual effects.It significantly increases the maximum temperature and the thermal desorption remediation efficiency in the superheated steam zone.However,it inhibits the development of the high temperature zone.These findings provide a theoretical foundation for optimizing the design of steam injection engineering.

       

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